From the MARDi Cascade to the Stereoselective Construction of Functionalized Bicyclo[5.4.0]undecene Skeletons Occurring in Natural Compounds

M.-   H.   Filippini; J.      Rodriguez

doi:10.2174/1570178043488716

Abstract

The stereoselective construction of functionalized bicyclo[5.4.0]undecene systems, found in many natural sesquiterpenes such as in the widdrane, guadalupane, and recently isolated guanacastepene families, is achieved by selective chemical transformations of a functionalized cycloheptanol arising from the MARDi cascade.

Keywords: mardi cascade, seven-membered rings, bicyclo[5.4.0]undecenes

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Letters in Organic Chemistry

Title: From the MARDi Cascade to the Stereoselective Construction of Functionalized Bicyclo[5.4.0]undecene Skeletons Occurring in Natural Compounds

Volume: 1 Issue: 1

Author(s): M.- H. Filippini and J. Rodriguez

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Keywords: mardi cascade, seven-membered rings, bicyclo[5.4.0]undecenes

Abstract: The stereoselective construction of functionalized bicyclo[5.4.0]undecene systems, found in many natural sesquiterpenes such as in the widdrane, guadalupane, and recently isolated guanacastepene families, is achieved by selective chemical transformations of a functionalized cycloheptanol arising from the MARDi cascade.

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Filippini H. M.- and Rodriguez J., From the MARDi Cascade to the Stereoselective Construction of Functionalized Bicyclo[5.4.0]undecene Skeletons Occurring in Natural Compounds, Letters in Organic Chemistry 2004; 1 (1) . https://dx.doi.org/10.2174/1570178043488716