P(t-Bu)3 : A Versatile and Efficient Ligand in Homogeneous Catalysis

Jean   Michel   Brunel

doi:10.2174/1570193043403163

Abstract

Changing substituents on phosphorus ligands can cause marked changes in the behaviour of the free ligands and of their transition metal complexes. In this review, we will describe the synthesis and the application of P(t-Bu)3, an efficient ligand in numerous homogeneous catalytic systems and rationalise its singular behaviour.

Keywords: tri-tert-butyl phosphine (p(t-bu)3), palladium, catalysis, amination, cross coupling

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Mini-Reviews in Organic Chemistry

Title: P(t-Bu)3 : A Versatile and Efficient Ligand in Homogeneous Catalysis

Volume: 1 Issue: 3

Author(s): Jean Michel Brunel

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Keywords: tri-tert-butyl phosphine (p(t-bu)3), palladium, catalysis, amination, cross coupling

Abstract: Changing substituents on phosphorus ligands can cause marked changes in the behaviour of the free ligands and of their transition metal complexes. In this review, we will describe the synthesis and the application of P(t-Bu)3, an efficient ligand in numerous homogeneous catalytic systems and rationalise its singular behaviour.

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Brunel Michel Jean, P(t-Bu)3 : A Versatile and Efficient Ligand in Homogeneous Catalysis, Mini-Reviews in Organic Chemistry 2004; 1 (3) . https://dx.doi.org/10.2174/1570193043403163