Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines having Electron-Withdrawing Substituents

Hideto      Miyabe; Akira      Matsumura; Kazumasa      Yoshida; Masashige      Yamauchi; Yoshiji      Takemoto

doi:10.2174/1570178043488464

Abstract

As a new direct functionalization of guanidines, the N-allylic substitution of guanidines was studied. The nitrogen atom of guanidine derivatives having two Nelectron- withdrawing substituents acted as a reactive nucleophile in the allylic substitution.

Keywords: guanidine, palladium, iridium, catalytic reaction, allylation, allylic substitution

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Letters in Organic Chemistry

Title: Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines having Electron-Withdrawing Substituents

Volume: 1 Issue: 2

Author(s): Hideto Miyabe, Akira Matsumura, Kazumasa Yoshida, Masashige Yamauchi and Yoshiji Takemoto

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Keywords: guanidine, palladium, iridium, catalytic reaction, allylation, allylic substitution

Abstract: As a new direct functionalization of guanidines, the N-allylic substitution of guanidines was studied. The nitrogen atom of guanidine derivatives having two Nelectron- withdrawing substituents acted as a reactive nucleophile in the allylic substitution.

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Miyabe Hideto, Matsumura Akira, Yoshida Kazumasa, Yamauchi Masashige and Takemoto Yoshiji, Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines having Electron-Withdrawing Substituents, Letters in Organic Chemistry 2004; 1 (2) . https://dx.doi.org/10.2174/1570178043488464