Abstract
A Barbier-type allylation of aldimines by allylic acetates in the presence of zinc dust and a simple cobalt halide catalyst takes place in acetonitrile to give the corresponding homoallylic amines in good yields.
Keywords: allylation, homo-allylic amines, imines, cobalt halide
Letters in Organic Chemistry
Title: Cobalt-Catalyzed Allylation of Aldimines by Allylic Acetates
Volume: 1 Issue: 2
Author(s): Paulo Gomes, Corinne Gosmini and Jacques Perichon
Affiliation:
Keywords: allylation, homo-allylic amines, imines, cobalt halide
Abstract: A Barbier-type allylation of aldimines by allylic acetates in the presence of zinc dust and a simple cobalt halide catalyst takes place in acetonitrile to give the corresponding homoallylic amines in good yields.
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Cite this article as:
Gomes Paulo, Gosmini Corinne and Perichon Jacques, Cobalt-Catalyzed Allylation of Aldimines by Allylic Acetates, Letters in Organic Chemistry 2004; 1 (2) . https://dx.doi.org/10.2174/1570178043488518
DOI https://dx.doi.org/10.2174/1570178043488518 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
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