Cycloaddition of Nitrones and Nitrile Oxides to Activated Exo-glycals

C.      Taillefumier; G.      Enderlin; Y.      Chapleur

doi:10.2174/1570178053765339

Abstract

The 3+2 cycloaddition reaction of nitrones and nitrile oxides with activated exo-glycals obtained from the Wittig reaction of sugar lactones gave good yields of only two cycloadducts. The reaction was efficiently carried out under microwave activation.

Keywords: dipolar cycloaddition, exo-glycals, spironucleosides, microwave activation

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Letters in Organic Chemistry

Title: Cycloaddition of Nitrones and Nitrile Oxides to Activated Exo-glycals

Volume: 2 Issue: 3

Author(s): C. Taillefumier, G. Enderlin and Y. Chapleur

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Keywords: dipolar cycloaddition, exo-glycals, spironucleosides, microwave activation

Abstract: The 3+2 cycloaddition reaction of nitrones and nitrile oxides with activated exo-glycals obtained from the Wittig reaction of sugar lactones gave good yields of only two cycloadducts. The reaction was efficiently carried out under microwave activation.

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Taillefumier C., Enderlin G. and Chapleur Y., Cycloaddition of Nitrones and Nitrile Oxides to Activated Exo-glycals, Letters in Organic Chemistry 2005; 2 (3) . https://dx.doi.org/10.2174/1570178053765339