Solvothermal In Situ Ligand Synthesis, Crystal Structure and Fluorescent Properties of a New Heterocyclic Compound 1, 1 - Bis{3-(Pyridin-2-yl)HImidazo[ 1, 5-a]Pyridine}

Title: Solvothermal In Situ Ligand Synthesis, Crystal Structure and Fluorescent Properties of a New Heterocyclic Compound 1, 1 - Bis{3-(Pyridin-2-yl)HImidazo[ 1, 5-a]Pyridine}

Volume: 2 Issue: 8

Author(s): Cai-Ming Liu, Hong-Yun Gao, De-Qing Zhang and Dao-Ben Zhu

Affiliation:

Keywords: Solvothermal synthesis, heterocyclic compound, imidazo[1, 5-a]pyridine compound, iron(II) complex, crystal structure, fluorescent property

Abstract: Solvothermal in situ ligand reaction of bis(2-pyridinylmethyl)amine (bpa) in the presence of Fe(ClO4)2 × 6H2O and NaN3 yielded the crystalline fluorescent organic heterocyclic compound 1, 1-bis{3- (pyridin-2-yl)H-imidazo[1, 5-a]pyridine} 1 and the byproduct Fe(bpa)2(ClO4)2 2. Compound 1 is the first example of imidazo[1, 5-a]pyridine compound synthesized by in situ reaction under solvothermal conditions.

Cite this article as:

Liu Cai-Ming, Gao Hong-Yun, Zhang De-Qing and Zhu Dao-Ben, Solvothermal In Situ Ligand Synthesis, Crystal Structure and Fluorescent Properties of a New Heterocyclic Compound 1, 1 - Bis{3-(Pyridin-2-yl)HImidazo[ 1, 5-a]Pyridine}, Letters in Organic Chemistry 2005; 2 (8) . https://dx.doi.org/10.2174/157017805774717427