The Reaction of Alkenes with AgNO2/TMSCL: The Synthesis of Oxadiazole-2-Oxides (Furoxans) Via Nitroso Nitrates

A.   S.   Demir; H.      Findik

doi:10.2174/157017805774296948

Abstract

The reaction of AgNO2/TMSCl with olefins affords nitrosonitrate, which are converted into α- nitroximes in good yield. Both nitrosonitrate and nitroximes are converted with acids into furoxane in high yield. The reaction of AgNO2 with TMSCl furnished first N2O3 and hexamethylsiloxane. The nitroso nitrates are obtained by addition of N2O3 to the olefines.

Keywords: nitrosonitrate, nitroximes, furoxane

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Letters in Organic Chemistry

Title: The Reaction of Alkenes with AgNO2/TMSCL: The Synthesis of Oxadiazole-2-Oxides (Furoxans) Via Nitroso Nitrates

Volume: 2 Issue: 7

Author(s): A. S. Demir and H. Findik

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Keywords: nitrosonitrate, nitroximes, furoxane

Abstract: The reaction of AgNO2/TMSCl with olefins affords nitrosonitrate, which are converted into α- nitroximes in good yield. Both nitrosonitrate and nitroximes are converted with acids into furoxane in high yield. The reaction of AgNO2 with TMSCl furnished first N2O3 and hexamethylsiloxane. The nitroso nitrates are obtained by addition of N2O3 to the olefines.

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Demir S. A. and Findik H., The Reaction of Alkenes with AgNO2/TMSCL: The Synthesis of Oxadiazole-2-Oxides (Furoxans) Via Nitroso Nitrates, Letters in Organic Chemistry 2005; 2 (7) . https://dx.doi.org/10.2174/157017805774296948