Highlights in Organic Chemistry [ Synthetic Applications of Multi-Component Coupling Reactions Proceeding Via Bis-π-Allylpalladium Complexes ]

Helena   C.   Malinakova

doi:10.2174/157017806775224323

Abstract

In this report, recently developed multi-component coupling reactions proceeding via symmetrical and unsymmetrical bis-π-allylpalladium complexes are reviewed. The transformations provided an efficient access to 1,7-octadienes, oxa- and aza-heterocycles, medium-size carbocycles, homoallylic alcohols and α,β- unsaturated-δ-lactones.

Keywords: carbon-carbon bonds, transformation, bisallylation, allylstannanes, palladium-catalyzed process, electrophile

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Letters in Organic Chemistry

Title: Highlights in Organic Chemistry [ Synthetic Applications of Multi-Component Coupling Reactions Proceeding Via Bis-π-Allylpalladium Complexes ]

Volume: 3 Issue: 2

Author(s): Helena C. Malinakova

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Keywords: carbon-carbon bonds, transformation, bisallylation, allylstannanes, palladium-catalyzed process, electrophile

Abstract: In this report, recently developed multi-component coupling reactions proceeding via symmetrical and unsymmetrical bis-π-allylpalladium complexes are reviewed. The transformations provided an efficient access to 1,7-octadienes, oxa- and aza-heterocycles, medium-size carbocycles, homoallylic alcohols and α,β- unsaturated-δ-lactones.

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Malinakova C. Helena, Highlights in Organic Chemistry [ Synthetic Applications of Multi-Component Coupling Reactions Proceeding Via Bis-π-Allylpalladium Complexes ], Letters in Organic Chemistry 2006; 3 (2) . https://dx.doi.org/10.2174/157017806775224323