An Efficient and Stereoselective Synthesis of 2-Deoxy Ketopyranoses from exo-Glycals

Pedro   A.   Colinas; Albrecht      Lieberknecht; Rodolfo   D.   Bravo; Agustin      Ponzinibbio

doi:10.2174/157017806777828457

Abstract

2-Deoxy ketopyranoses were prepared in very good yields and excellent stereoselectivity by a onepot procedure involving the iodohydroxylation of exo-glycals and removal of the iodide group using sodium dithionite.

Keywords: Sodium dithionite, Stereoselectivity, Ketopyranose, Iodohydroxylation, exo-Glycal

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Letters in Organic Chemistry

Title: An Efficient and Stereoselective Synthesis of 2-Deoxy Ketopyranoses from exo-Glycals

Volume: 3 Issue: 6

Author(s): Pedro A. Colinas, Albrecht Lieberknecht, Rodolfo D. Bravo and Agustin Ponzinibbio

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Keywords: Sodium dithionite, Stereoselectivity, Ketopyranose, Iodohydroxylation, exo-Glycal

Abstract: 2-Deoxy ketopyranoses were prepared in very good yields and excellent stereoselectivity by a onepot procedure involving the iodohydroxylation of exo-glycals and removal of the iodide group using sodium dithionite.

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Colinas A. Pedro, Lieberknecht Albrecht, Bravo D. Rodolfo and Ponzinibbio Agustin, An Efficient and Stereoselective Synthesis of 2-Deoxy Ketopyranoses from exo-Glycals, Letters in Organic Chemistry 2006; 3 (6) . https://dx.doi.org/10.2174/157017806777828457