Tetra-n-Propylammonium Perruthenate (TPAP) Catalyzed Aerobic Oxidation of Hydroxylamines to Nitrones

Francesca      Cardona; Lapo      Gorini; Andrea      Goti

doi:10.2174/157017806775224215

Abstract

A novel aerobic, environmentally friendly oxidation of hydroxylamines to nitrones catalyzed by tetra-n-propylammonium perruthenate (TPAP) is reported. Complete conversions and reasonable to excellent yields were obtained for cyclic hydroxylamines.

Keywords: Oxidation, nitrogen containing compounds, environmentally friendly, oxygen, catalysis

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Letters in Organic Chemistry

Title: Tetra-n-Propylammonium Perruthenate (TPAP) Catalyzed Aerobic Oxidation of Hydroxylamines to Nitrones

Volume: 3 Issue: 2

Author(s): Francesca Cardona, Lapo Gorini and Andrea Goti

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Keywords: Oxidation, nitrogen containing compounds, environmentally friendly, oxygen, catalysis

Abstract: A novel aerobic, environmentally friendly oxidation of hydroxylamines to nitrones catalyzed by tetra-n-propylammonium perruthenate (TPAP) is reported. Complete conversions and reasonable to excellent yields were obtained for cyclic hydroxylamines.

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Cardona Francesca, Gorini Lapo and Goti Andrea, Tetra-n-Propylammonium Perruthenate (TPAP) Catalyzed Aerobic Oxidation of Hydroxylamines to Nitrones, Letters in Organic Chemistry 2006; 3 (2) . https://dx.doi.org/10.2174/157017806775224215