Abstract
This review presents the development of Palladium-catalyzed oxidative Heck reactions of organometallic compounds (OMCs) with alkenes. The mechanism is discussed with many experimental studies. OMCs derived from Group III to Group VII are shown to be efficient substrates for the oxidative Heck reaction.
Keywords: Palladium-catalyzed, oxidative Heck reaction, organometallic compounds, olefins, transmetallation, base, ligand, oxidant, organoboronic acids, organosillicon compounds, organotin compounds, Arylboronic Acids, chemoselectivity, regioselectivity, stereoselectivity, catalyst developments
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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