Abstract
Regioisomers of calixarenes can be either produced in the reaction process with the same reactants or derived from the isomeric nucleophilic reagents. This article reviews the syntheses, different complexation abilities and self-assembly behaviors of the regioisomers in calixarenes.
Keywords: Calixarene, regioisomer, synthesis, self-assembly, complexation, isomeric nucleophilic reagents, supramolecular chemistry, bonds, p-tert-butylcalix, acetonitrile, benzyl bromide, thermodynamic parameters, calorimetric methods, calixcrowns, ethylenediamine, triethylene glycol ditosylate, bistosyloxyetboxybenzene, trans-stilbene, Fluorescence spectra, bromopyridines, N-methylpyridinium, tetramethylammonium, tosyloxyethoxy, X-ray diffraction, benzocrowns
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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