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Current Analytical Chemistry

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ISSN (Print): 1573-4110
ISSN (Online): 1875-6727

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Research Article

Luminescence Detection of Cr3+, Bi3+, and Acetone in Aqueous Solution by Core-Shell Tb-MOF

In Press, (this is not the final "Version of Record"). Available online 06 June, 2024
Author(s): Mengfei Yang, Jing Shi, Taiming Luo* and Xiaozhan Yang*
Published on: 06 June, 2024

DOI: 10.2174/0115734110297005240531055254

Price: $95

Abstract

Aims: By using terephthalic acid, 2, 5-furandicarboxylic acid, and terbium nitrate hexahydrate, a Tb-MOF with a core-shell structure was successfully designed and prepared.

Method: A one-pot method was employed to design and synthesize core-shell Tb-MOF. The morphology, luminescence performance, and stability were well characterized.

Results: Tb-MOF demonstrated good water stability, acid and alkali resistance, and thermal stability. Tb-MOF was found to have high sensitivity to detect Cr3+, Bi3+, and acetone in an aqueous solution, and the LOD of Cr3+, Bi3+, and acetone were calculated to be 0.18 μM, 4.22 μM, and 0.26%, respectively. The sensing mechanism of Cr3+ and acetone was explained as energy-competitive absorption, and the sensing mechanism of Bi3+ was explained as ion replacement.

Conclusion: The prepared Tb-MOF can be developed as a multifunctional light-emitting sensor with high selectivity.

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