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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

L-Proline Nitrate: An Efficient Amino Acid Ionic Liquid Catalyzed Synthesis of 5-aryl-[1, 2, 4]-triazolidine-3-thiones

Author(s): Suraj A. Sonawane and Dattaprasad M. Pore*

Volume 19, Issue 9, 2022

Published on: 10 March, 2022

Page: [743 - 749] Pages: 7

DOI: 10.2174/1570178619666220128141519

Price: $65

Abstract

An environmentally benign, simple, rapid synthesis of 1,2,4-triazolidine-3-thiones at room temperature is reported using amino acid-derived Brønsted acidic ionic liquid L-proline nitrate [Pro+NO3 -] from aldehyde and thiosemicarbazide in an aqueous medium. A cost-effective and energy-efficient catalyst with the reusability of up to five cycles without significant loss in the catalytic activity makes this protocol superior. A faster reaction and easy work-up with excellent yields are the added advantages of this protocol.

Keywords: Ionic liquid, proline nitrate, reusability, biodegradable, cost-effective, amino acid.

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