Abstract
Whether in supercritical CO2 or in organic solvent and using O2 or aqueous H2O2 as primary oxidants, the series of sol-gel entrapped TPAP hybrid silica gels is a versatile class of oxidation catalysts suitable for the highly selective conversion of alcohols to carbonyls. These materials are generally more stable and active than traditional polymersupported analogues. This report summarizes recent findings showing the large potential of this technology for synthetic chemistry.
Keywords: oxoruthenate catalyst, dehydrogenation, FluoRuGel, aerobic oxidation, sol-gel process
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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