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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

Magnetic Organic-Inorganic Hybrid Nano System Anchored Platinum Nanoparticles for Carbon Sequestration Reaction

Author(s): Praveenkumar Ramprakash Upadhyay, Prashant Gautam and Vivek Srivastava*

Volume 17, Issue 1, 2020

Page: [73 - 83] Pages: 11

DOI: 10.2174/1570178616666190228141754

Price: $65

Abstract

A new Pt metal based nano-catalytic system was developed using organic-inorganic magnetic framework followed by the user-friendly protocol in good yield. XRD, FTIR, TEM, BET, ICP-OES and solid-state NMR techniques were used to characterize our developed catalytic system. The wellcharacterized ionic liquid bridged-silica supported magnetic Pt nanoparticles were utilized for the selective hydrogenation of carbon dioxide under high-pressure reaction condition (with and without ionic liquid medium). Most promising results were obtained while using the catalytic system (Pt-MagNP@ILSiO2) in 1,3-di (N, N-dimethylaminoethyl)-2-methylimidazolium nonafluorobutanesulfonate ([DAMI] [CF3CF2CF2CF2SO3]) task-specific ionic liquid medium. This TSIL not only provided a high degree of CO2 absorption during the reaction but also enhances the selectivity and the recyclability of the catalytic system up to 8 runs. No sign of Pt metal leaching was recorded during the recyclability test which confirmed the stability of this catalytic system under high-pressure reaction condition.

Keywords: Carbon dioxide, ionic liquid, formic acid, magnetic nanoparticles, silica, Pt NPs.

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