Abstract
This review provides a survey of Atom Transfer Radical Addition (ATRA) and Atom Transfer Radical Polymerization (ATRP) with the special emphasis on the copper mediated processes. Mechanistic features of these techniques are reviewed together with the major components of ATRP and examples of materials prepared by ATRP.
Keywords: Atom Transfer Radical Addition (ATRA), Atom Transfer Radical Polymerization (ATRP), thermal decomposition, Acetonitrile, Ethyl acetate, inner-sphere electron transfer (ISET), 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO), dimethylaminoethyl
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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