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Current Environmental Engineering

Editor-in-Chief

ISSN (Print): 2212-7178
ISSN (Online): 2212-7186

Review Article

Removal of Refractory Organic Compounds from Wastewater by Various Advanced Oxidation Process - A Review

Author(s): Manjari Srivastav*, Meenal Gupta, Sushil K. Agrahari and Pawan Detwal

Volume 6, Issue 1, 2019

Page: [8 - 16] Pages: 9

DOI: 10.2174/2212717806666181212125216

Abstract

Per capita average annual freshwater availability is gradually reduced due to increasing population, urbanization and affluent lifestyles. Hence, management of wastewater is of great concern. The wastewater from different industries can be treated by various conventional treatment methods but these conventional treatment technologies seem to be ineffective for the complete removal of pollutants especially refractory organic compounds that are not readily biodegradable in nature. Detergents, detergent additives, sequestering agents like EDTA, Pesticides, Polycyclic aromatic hydrocarbons, etc. are some of the recalcitrant organic compounds found in the wastewater. One of the treatment technologies for the removal of recalcitrant organic compounds is Advanced Oxidation Process (AOP). The production of hydroxyl free radical is the main mechanism for the AOP. AOP is a promising technology for the treatment of refractory organic compounds due to its low oxidation selectivity and high reactivity of the radical. Hydrogen peroxide (H2O2), Ozonation, Ultra-violet (UV) radiation, H2O2/UV process and Fenton’s reaction are extensively used for the removal of refractory organic compounds thus reducing Chemical Oxygen Demand (COD), Total Organic Carbon (TOC), phenolic compounds, dyes etc. to great extent. From the studies, we found that Fenton’s reagents appear to be most economically practical AOP systems for almost all industries with respect to high pollutant removal efficiency and it is also economical. From the energy point of view, the ozone based process proves to be more efficient but it is costlier than the Fenton’s process.

Keywords: Advanced oxidation process, refractory organic compounds, wastewater, hydroxyl free radical, ultraviolet radiation, Polycyclic aromatic hydrocarbons.

Graphical Abstract

[1]
Krishnan S, Rawindran H, Sinnathambi CM, Lim JW. Comparison of various advanced oxidation processes used in remediation of industrial wastewater laden with recalcitrant pollutants. IOP Conference Series 2017 206.
[http://dx.doi.org/10.1088/1757-899X/206/1/012089]
[2]
Valderrama LT, Del Campo CM, Rodriguez CM, De-Bashan LE, Bashan Y. Treatment of refractory wastewater from ethanol and citric acid production using the microalga Chlorella vulgaris and the macrophyte Lemna minuscula. Water Res 2002; 36: 4185-92.
[3]
Lei L, Chen S, Li Y. Effect of biological treatment on characteristics of soluble organic compounds in hardwood KP bleaching effluent. Biol Res 2013; 8: 4349-58.
[4]
Thanekar P, Panda M, Gogate PR. Degradation of carbamazepine using hydrodynamic cavitation combined with advanced oxidation processes. Ultrason Sonochem 2018; 40: 567-76.
[5]
Boczkaj G, Fernandes A. Wastewater treatment by means of advanced oxidation processes at basic pH: A review conditions. Chem Eng J 2017; 320: 608-33.
[6]
Deng Y, Zhao R. Advanced oxidation processes in wastewater treatment. Curr Pollut Rep 2015; 1(3): 167-76.
[7]
Mohajerani M, Mehrvar M, Ein-Mozaffari F. An overview of the integration of advanced oxidation technologies and other processes for water and wastewater treatment. Int J Eng 2009; 3: 120-46.
[8]
Antonopoulou M, Evgenidou E, Lambropoulou D, Konstantinou I. A review on advanced oxidation processes for the removal of taste and odour compounds from aqueous media. Water Res 2014; 53: 215-34.
[9]
Huang CP, Dong C, Tang Z. Advanced chemical oxidation: Its present role and potential future in hazardous waste treatment. Waste Manag 1993; 13(5-7): 361-77.
[10]
Mazille F, Spuhler D. Advanced oxidation processes. SSWM University Course 2018. Available from: https://sswm.info/sswm-university-course/module-6-disaster-situations-planning-and-preparedness/further-resources-0/advanced-oxidation-processes (Accessed on April 2nd, 2018)
[11]
Munter R. Advanced oxidation processes-current status and prospects. Proc Estonian Acad Sci Chem 2001; 50(2): 59-80.
[12]
Andreozzi R, Caprio V, Insola A, Marotta R. Advanced Oxidation Processes (AOP) for water purification and recovery. Catal Today 1999; 53: 51-9.
[13]
Inchaurrondo N, Cechini J, Font J, Haure P. Strategies for enhanced CWPO of phenol solutions. Appl Catal B Environ 2012; 112: 641-8.
[14]
Kommineni S, Zoeckler J, Stocking A, et al. Advanced oxidation processes. In: National Water Research Institute. (Accessed on June 21, 2011).
[15]
Massa P, Dafinov A, Medina CF, Fenoglio R. Catalytic wet peroxide oxidation of phenolic solutions over Fe2O3/CeO2 and WO3/CeO2 catalyst systems. Cat Comm 2009; 9: 1533-8.
[16]
Ikehata K, El-Din MG. Degradation of refractory surfactants in wastewater by ozonation and advanced oxidation processes: A review. Ozone Sci Eng 2004; 26(4): 327-43.
[17]
Paphane BD, Ramirez LL. Chemical pre-treatment of anionic surfactants contaminated waste water at enaspol AS using H2O2/UV light waste water pre-treatment method. J Environ Anal Toxicol 2013; 3(181): 2161-525.
[18]
Bokare AD, Choi W. Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes. J Hazard Mater 2014; 275: 121-35.
[19]
Alam MG, Tawfik A, Ookawara S. Investigation of optimum conditions and costs estimation for degradation of phenol by solar photo-fenton process. Appl Water Sci 2017; 7(1): 375-82.
[20]
Cortes S, Sarasa J, Ormad P, Gracia R, Ovelleiro J. Comparative efficiency of the systems O3/high pH and O3/CAT for the oxidation of chlorobenzenes in water. Ozone Sci Eng 2000; 22(4): 415-26.
[21]
Krzeminska D, Neczaj E, Borowski G. Advanced oxidation processes for food industrial. J Ecol Eng 2015; 16: 61-71.
[22]
Rice RG. Applications of ozone for industrial wastewater treatment. A review. Ozone Sci Eng 1996; 18(6): 477-515.
[23]
Friedrich M. Actual development of ozone technology, explained with examples for treatment of chemical wastewater with ozone. In: Proceeding of 12th Ozone World Congress of IOA 1995 2; 469-76.
[24]
Raj CC, Quen HL. Advanced oxidation processes for wastewater treatment: Optimization of UV/H2O2 process through a statistical technique. Chem Eng Sci 2005; 60(9): 5305-11.
[25]
Rodriguez JB, Mutis A, Yeber MC, Freer J, Baeza J, Mansilla HD. Chemical degradation of EDTA and DTPA in a Totally Chlorine Free (TCF) effluent. Water Sci Technol 1999; 40: 267-72.
[26]
Akpan UG, Hameed BH. Parameters affecting the photocatalytic degradation of dyes using TiO2 -based photocatalysts: A review. J Hazard Mater 2009; 170: 520-9.
[27]
Buthiyappan A, Aziz ARA, Daud WMAW. Recent advances and prospects of catalytic advanced oxidation process in treating textile effluents. Rev Chem Eng 2016; 32(1): 1-47.
[28]
Canizares P, Paz R, Saez C, Rodrigo MA. Costs of the electrochemical oxidation of wastewaters: A comparison with ozonation and fenton oxidation processes. J Environ Manage 2009; 90(1): 410-20.
[29]
Covinich LG, Bengoechea DI, Fenoglio RJ, Area MC. Advanced oxidation processes for wastewater treatment in the pulp and paper industry: A review. Am J Environ Eng 2014; 4(3): 56-70.
[30]
Moro GD, Mancini A, Mascolo G, Iaconi CD. Comparison of UV/H2O2 based AOP as an end treatment or integrated with biological degradation for treating landfill leachates. Chem Eng J 2013; 218: 133-7.
[31]
Manenti DR, Modenes A, Soares P, et al. Assessment of a multistage system based on electrocoagulation, solar photo Fenton and biological oxidation processes for real textile wastewater. Chem Eng J 2014; 252: 120-30.
[32]
Sirtori C, Zapata A, Oller I, Gernjak W, Aguera A, Malato S. Decontamination industrial pharmaceutical wastewater by combining solar photo-Fenton and biological treatment. Water Res 2009; 43: 661-8.
[33]
Bijan L, Mohsen M. Integrated ozone and biotreatment of pulp mill effluent and changes in biodegradability and molecular weight distribution of organic compounds. Water Res 2005; 39(16): 3763-72.
[34]
Nishijima W, Okada M. Improvement of DOC removal by multi-stage AOP-biological treatment. Chemosphere 2003; 50(8): 1043-8.
[35]
Saroj DP, Kumar A, Bose P, Tare V. Enhancement in mineralization of some natural refractory organic compounds by ozonation-aerobic biodegradation. J Chem Technol Biotechnol 2006; 81: 115-27.
[36]
Mahamuni NN, Adewuyi YG. Advanced Oxidation Processes (AOPs) involving ultrasound for waste water treatment: A review with emphasis on cost estimation. Ultrason Sonochem 2010; 17(6): 990-1003.
[37]
Zimmermann FJ. New waste disposal process. Chem Eng 1985; 65: 117-20.
[38]
Mishra VS, Mahajani VV, Joshi JB. Wet air oxidation. Ind Eng Chem Res 1995; 34(1): 2-48.
[39]
Luan M, Jing G, Piao Y, Liu D, Jin L. Treatment of refractory organic pollutants in industrial wastewater by wet air oxidation. Arab J Chem 2017; 10: S769-.
[40]
Zhou MH, He JJ. Degradation of azo dye by three clean advanced oxidation processes: Wet oxidation, electrochemical oxidation and wet electrochemical oxidation. A comparative study. Electrochim Acta 2007; 53: 1902-10.
[41]
Tang WW, Zeng XP, Zhao JF, Gu GW, Li YJ, Ni YM. The study on the wet air oxidation of highly concentrated emulsified wastewater and its kinetics. Separ Purif Tech 2003; 31: 77-82.
[42]
Shah IP, Khambete AK. Tertiary treatment of bulk drug effluent containing bio-refractory cod by electrochemical oxidation using Boron Doped Diamond (BDD) Electrode. In: 2nd International Conference on Chemical, Biological and Environment Sciences (ICCEBS 2012) June 30-July 1, Bali; pp. 66-9.

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