Abstract
Alkenylaluminum reagents are good nucleophiles for organic reactions because of their high reactivities, the high Lewis acidity of the aluminum center, and their low toxicities. Therefore, alkenylaluminum reagents are widely applied in many of organic reactions. This review summarizes the recent advance of the alkenylaluminum reagents applied in cross-coupling reactions, involving various reaction systems, properties of reaction and synthetic application.
Keywords: Alkenylaluminum reagents, Cross-coupling reaction, C-C bond formation, C-N bond formation, research progress, nucleophiles.
Graphical Abstract
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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