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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

Cu(OAc)2-Promoted Thiolation and Selenylation of C(sp2)-H Bonds Using a 2-Amino Oxazole Directing Group

Author(s): R. Uday Kumar, Kommula Dileep, K. Harsha Vardhan Reddy* and Y.V.D. Nageswar*

Volume 16, Issue 2, 2019

Page: [110 - 116] Pages: 7

DOI: 10.2174/1570178615666180627111437

Price: $65

Abstract

Cu-catalyzed thiolation or selenylation of aryl C-H bonds with diaryl disulfides and diphenyl diselenides was accomplished using a readily removable directing group. This protocol represents a convenient route for the formation of valuable diaryl sulfides or diphenyl selenides. This simple method gives a variety of functionalized diphenyl sulfides or diphenyl selenides in moderate to good yields in a simple and efficient way.

Keywords: Diphenyl disulfide/diselenide, directing group, C-H activation, thiolation, selenylation, redox properties.

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