Dichlorophenobarbital: An Efficient and Selective Reagent for Deoximation of Oximes to the Carbonyl Compounds

Azam        Shiri; Ahmad         Khoramabadi-zad; Fateme         Esmaili-Nezhad

doi:10.2174/1570178615666180413125305

Abstract

A simple, fast and efficient procedure for the cleavage of a wide of range ketoximes and aldoximes to the corresponding compounds using a safe and low-cost reagent, N,N′-dichlorophenobarbital, under mild reaction conditions at room temperature is described.

Keywords: Deoximation, N, N′-dichlorophenobarbital, oximes, aldehydes, ketones, crystalline compound.

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Letters in Organic Chemistry

Title:Dichlorophenobarbital: An Efficient and Selective Reagent for Deoximation of Oximes to the Carbonyl Compounds

Volume: 15 Issue: 10

Author(s): Azam Shiri, Ahmad Khoramabadi-zad*Fateme Esmaili-Nezhad

Affiliation:

Faculty of Chemistry, Bu-Ali Sina University, Hamedan 65178-38695,Iran

Keywords: Deoximation, N, N′-dichlorophenobarbital, oximes, aldehydes, ketones, crystalline compound.

Abstract: A simple, fast and efficient procedure for the cleavage of a wide of range ketoximes and aldoximes to the corresponding compounds using a safe and low-cost reagent, N,N′-dichlorophenobarbital, under mild reaction conditions at room temperature is described.

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Shiri Azam , Khoramabadi-zad Ahmad *, Esmaili-Nezhad Fateme , Dichlorophenobarbital: An Efficient and Selective Reagent for Deoximation of Oximes to the Carbonyl Compounds, Letters in Organic Chemistry 2018; 15 (10) . https://dx.doi.org/10.2174/1570178615666180413125305

DOI https://dx.doi.org/10.2174/1570178615666180413125305	Print ISSN 1570-1786
Publisher Name Bentham Science Publisher	Online ISSN 1875-6255