Copper-catalyzed Synthesis of a Novel Inherently Chiral Calix[4]arene Pyrazine Derivative

Title:Copper-catalyzed Synthesis of a Novel Inherently Chiral Calix[4]arene Pyrazine Derivative

Volume: 15 Issue: 11

Author(s): Forouzandeh Razaghian, Saeed Taghvaei-Ganjali*, Mohammad Mahmoodi Hashemi, Reza Zadmard and Shahram Moradi Dehaghi

Affiliation:

• Department of Chemistry, Islamic Azad University, North Tehran Branch, Postal Code: 1913674711, Tehran,Iran

Keywords: Pyrazine, inherent chirality, copper catalyst, calix[4]arene, michael addition, spectroscopies.

Abstract: Inherently chiral pyrazine derivative of calix[4]arene was synthesised from calixquinone derivative and ethylenediamine in the presence of copper (II) acetate as a racemate. The obtained molecule was characterised by various spectroscopic methods such as: 1H NMR, 13C NMR, HH-COSY and IR spectroscopies.

Cite this article as:

Razaghian Forouzandeh , Taghvaei-Ganjali Saeed *, Hashemi Mahmoodi Mohammad, Zadmard Reza and Dehaghi Moradi Shahram, Copper-catalyzed Synthesis of a Novel Inherently Chiral Calix[4]arene Pyrazine Derivative, Letters in Organic Chemistry 2018; 15 (11) . https://dx.doi.org/10.2174/1570178615666180412121751