Hydrosilylation of Olefins with the Cp2TiCl2/Sm Catalytic System

Title:Hydrosilylation of Olefins with the Cp2TiCl2/Sm Catalytic System

Volume: 15 Issue: 12

Author(s): Xiaoling Yang, Ying Bai*, Jiayun Li, Yu Liu and Jiajian Peng*

Affiliation:

• Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121,China

• Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121,China

Keywords: Alkene, catalytic, hydrosilylation, samarium, solvent-free, titanocene.

Abstract: Hydrosilylation of olefins catalyzed by Cp2TiCl2/Sm (Cp = cyclopentadienyl) under solventfree conditions has been investigated. The mole ratio of Cp2TiCl2/Sm has some influence on the catalytic properties, and the best Cp2TiCl2/Sm ratio for the catalytic hydrosilylation is 1/2. By using this catalytic system, hydrogenation products were also detected in the final reaction mixtures.

Cite this article as:

Yang Xiaoling , Bai Ying *, Li Jiayun , Liu Yu and Peng Jiajian *, Hydrosilylation of Olefins with the Cp2TiCl2/Sm Catalytic System, Letters in Organic Chemistry 2018; 15 (12) . https://dx.doi.org/10.2174/1570178615666180212160523