摘要
本文综述了银汞合金电极的特点及其在药物和维生素电分析中的应用。介绍了长期使用和使用方便的固体银汞合金电极的制备和建造技术。银汞合金虽然不像其他电极材料那样广泛应用,但它具有独特而可行的电化学性能组合,其性能接近理想的汞电极,无毒、耐久性高、机械稳定性好。它在极负电位下进行氧化还原过程的能力对于分析大量的生物活性有机化合物是必不可少的。该综述还概述了药物或维生素分析中的每一种应用的信息,根据银汞合金电极的结构变体分为各部分。
关键词: 银汞合金电极,药物,维生素,药品,临床分析,食品分析
Current Medicinal Chemistry
Title:Recent Applications of Silver Amalgam Electrodes for Analysis of Pharmaceuticals and Vitamins
Volume: 25 Issue: 33
关键词: 银汞合金电极,药物,维生素,药品,临床分析,食品分析
摘要: The features and applications of silver amalgam electrodes in electroanalysis of pharmaceuticals and vitamins are summarized in this review. The state-of-the-art in the preparation and construction of solid silver amalgam electrodes for prolonged and userfriendly use is presented. Although not as widely spread as other electrode materials, silver amalgam possesses a unique and viable combination of favorable electrochemical properties, which are close to ideal mercury electrodes, non-toxic character, high durability and mechanical stability, if properly prepared. Its capability of conducting the redox processes at highly negative potentials is essential for the analysis of large number of bioactive organic compounds. The review features also overview information for each application in drug or vitamin analysis divided to the sections according to the construction variants of silver amalgam electrodes.
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Cite this article as:
Recent Applications of Silver Amalgam Electrodes for Analysis of Pharmaceuticals and Vitamins, Current Medicinal Chemistry 2018; 25 (33) . https://dx.doi.org/10.2174/0929867324666170920143245
DOI https://dx.doi.org/10.2174/0929867324666170920143245 |
Print ISSN 0929-8673 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-533X |
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