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Current Catalysis

Editor-in-Chief

ISSN (Print): 2211-5447
ISSN (Online): 2211-5455

Synthesis, Characterization and Catalytic Activity of a Novel 2-(3′- Aminophenyl) Benzimidazoyl Palladium (II) Complex

Author(s): K. Lokesh, S. HariPrasad, B. Roopashree and V. Gayathri

Volume 4, Issue 2, 2015

Page: [125 - 132] Pages: 8

DOI: 10.2174/2211544704666150508221808

Price: $65

Abstract

The synthesis and characterization of a novel aminophenyl benzimidazole Pd (II) complex is reported. The complex proved as an efficient catalyst for the Sonogashira crosscoupling reaction of ten different aryl bromides with trimethylsilylethyne to yield a wide range of aryl trimethylsilylethynes. The reaction involves use of the novel complex and triethylamine

Keywords: Benzimidazole, binuclear complex, cross-coupling reaction, coordination induced shift, trimethylsilylethynes.

Graphical Abstract


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