Fe³⁺ - Ion Selective Electrode Developed as a Detector in Flow Injection Analysis

Title:Fe³⁺ - Ion Selective Electrode Developed as a Detector in Flow Injection Analysis

Volume: 11 Issue: 2

Author(s): Ersin Demir, Barıs Kemer, Ibrahim Isildak and Hassan Y. Aboul-Enein

Affiliation:

Keywords: Iron-selective electrode, determination, flow injection system, potentiometer, syrups analysis.

Abstract: A new polyvinyl chloride (PVC) membrane Fe³⁺ ion selective electrode was constructed as a detector for the analysis Fe³⁺ using a home-made low-volume flow through cell. Optimum working conditions for the flow injection analysis (FIA) measurements were examined. In addition, under optimum conditions, potentiometric performance characteristics of the Fe³⁺ ion-selective electrode were investigated. Electrode had a linear response in the concentration range of 1.0 x 10^-3-1.0 x 10^-6 M (R²=0.9961, y=24.7+772.0). Reproducibility of the electrode responses was very satisfied. The potential of Fe³⁺ ion selective electrode was decreased intra and inter day 0.9 % and 3.7% respectively. The designed flowthrough cell system as Fe³⁺ detector revealed sampling rates of approximately 50 injections per hour. The obtained results in FIA were in a good agreement with AAs results at %95 confidence level for each syrups.

Cite this article as:

Demir Ersin, Kemer Barıs, Isildak Ibrahim and Aboul-Enein Y. Hassan, Fe³⁺ - Ion Selective Electrode Developed as a Detector in Flow Injection Analysis, Current Analytical Chemistry 2015; 11 (2) . https://dx.doi.org/10.2174/1573411011666150128193424