Higher Efficiently Conversion of Heterocyclic Aryl Nitroalkenes to Ketones

Dushu      Huang; Jin-Gang      Yu; Wei      Liu; Yunhui      Long; Jing      Wang

doi:10.2174/1570179411666140424232227

Abstract

Ketones were prepared by a modified Nef reaction using heterocyclic aryl nitroalkenes to react in a Fe-FeCl₃-CH₃COOH mixture with higher yield over 50% in sharp contrast with in Fe-HCl mixture with lower yield less than 30%, thus it’s cost-saving and relative environment friendly.

Keywords: Heterocyclic aryl nitroalkenes, Fe-FeCl₃-CH₃COOH system, ketones, Nef reaction, reductive hydrolysis.

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Current Organic Synthesis

Title:Higher Efficiently Conversion of Heterocyclic Aryl Nitroalkenes to Ketones

Volume: 11 Issue: 6

Author(s): Dushu Huang, Jin-Gang Yu, Wei Liu, Yunhui Long and Jing Wang

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Keywords: Heterocyclic aryl nitroalkenes, Fe-FeCl₃-CH₃COOH system, ketones, Nef reaction, reductive hydrolysis.

Abstract: Ketones were prepared by a modified Nef reaction using heterocyclic aryl nitroalkenes to react in a Fe-FeCl₃-CH₃COOH mixture with higher yield over 50% in sharp contrast with in Fe-HCl mixture with lower yield less than 30%, thus it’s cost-saving and relative environment friendly.

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Huang Dushu, Yu Jin-Gang, Liu Wei, Long Yunhui and Wang Jing, Higher Efficiently Conversion of Heterocyclic Aryl Nitroalkenes to Ketones, Current Organic Synthesis 2014; 11 (6) . https://dx.doi.org/10.2174/1570179411666140424232227

DOI https://dx.doi.org/10.2174/1570179411666140424232227	Print ISSN 1570-1794
Publisher Name Bentham Science Publisher	Online ISSN 1875-6271