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Current Physical Chemistry

Editor-in-Chief

ISSN (Print): 1877-9468
ISSN (Online): 1877-9476

Features of Near- and Supercritical Water

Author(s): Rudi P. Nielsen and Erik G. Søgaard

Volume 3, Issue 4, 2013

Page: [501 - 507] Pages: 7

DOI: 10.2174/18779468113036660010

Price: $65

Abstract

At elevated temperatures and pressures substances may become supercritical. Supercritical fluids have properties resembling both gasses and liquids, meaning that these fluids are interesting for various applications. This work describes some general aspects of the supercritical phase and the properties of near and supercritical water. The properties of supercritical water are related to the changes in dielectric constant, auto-dissociation of water and the significant decrease in the degree of hydrogen bonding at supercritical conditions.

Keywords: Supercritical water, phase transitions, hydrogen bonding


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