Abstract
This brief review deals with the recent progress in the implimentation of thio-Claisen rearrangement in synthetic organic chemistry. Thio-Claisen rearrangement has been utilized for the synthesis of many heterocyclic moieties of biological significance. Stereoselectivity of the thio-Claisen rearrangement has also been discussed. This short report mainly covers the literature published during 2003 onwards.
Keywords: Thio-Claisen rearrangement, thermal Claisen-rearrangement, catalyzed-Claisen rearrangement, asymmetric rearrangement, sulfur heterocycles, regioselective synthesis, stereoselective synthesis, electrocyclization, [3, 3]-sigmatropic shift, cyclodextrin, dihydroflustramine C, sequential Claisen rearrangement, [Rh2((S)-tbsp)4].
Current Organic Synthesis
Title:Recent Advancement of the thio-Claisen Rearrangement
Volume: 9 Issue: 6
Author(s): Krishna C. Majumdar, Srikanta Samanta, Buddhadeb Chattopadhyay and Nilasish Pal
Affiliation:
Keywords: Thio-Claisen rearrangement, thermal Claisen-rearrangement, catalyzed-Claisen rearrangement, asymmetric rearrangement, sulfur heterocycles, regioselective synthesis, stereoselective synthesis, electrocyclization, [3, 3]-sigmatropic shift, cyclodextrin, dihydroflustramine C, sequential Claisen rearrangement, [Rh2((S)-tbsp)4].
Abstract: This brief review deals with the recent progress in the implimentation of thio-Claisen rearrangement in synthetic organic chemistry. Thio-Claisen rearrangement has been utilized for the synthesis of many heterocyclic moieties of biological significance. Stereoselectivity of the thio-Claisen rearrangement has also been discussed. This short report mainly covers the literature published during 2003 onwards.
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Cite this article as:
Majumdar C. Krishna, Samanta Srikanta, Chattopadhyay Buddhadeb and Pal Nilasish, Recent Advancement of the thio-Claisen Rearrangement, Current Organic Synthesis 2012; 9 (6) . https://dx.doi.org/10.2174/157017912803901682
DOI https://dx.doi.org/10.2174/157017912803901682 |
Print ISSN 1570-1794 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6271 |
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