Abstract
This updated version of a 2008 review presents work in the still developing field of dehydrogenative coupling reactions of phosphines. Catalytic phosphorus–element bond formation via dehydrocoupling has rapidly expanded since the first discoveries in the mid 1990s. A survey of the available catalysts, P–P and P–E products, and mechanistic understanding is presented with emphasis on the emerging synthetic applications of this reaction.
Keywords: Dehydrocoupling, Phosphine, Heterodehydrocoupling, Bond-forming, Catalysis, Transition metal, micron-scale, Filtration, dihydroxylation, Stoichiometric, C–C bond activation, arylrhodium, stereoselectivities, tohormones
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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