Exceptionally Selective Catalytic Hydrogenation of Alkene with Pinacolborane

Joanna Niziol, Tomasz Ruman

doi:10.2174/157017812800233723

Abstract

The catalytic hydrogenation of model alkene – cyclohexene with the use of pinacolborane is reported along with the characterization of various side products. The non-standard hydrogenation product was obtained in high yield and purity under very mild reaction conditions with the use of iridium catalyst. The exceptionally high selectivity of the hydrogenation process is described for the first time in literature.

Keywords: Borane, Catalysis, Hydrogenation, Iridium, Pinacolborane, high temperatures, pressures, olefins, ethylene, sulfide

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Letters in Organic Chemistry

Title:Exceptionally Selective Catalytic Hydrogenation of Alkene with Pinacolborane

Volume: 9 Issue: 4

Author(s): Joanna Niziol, Tomasz Ruman

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Keywords: Borane, Catalysis, Hydrogenation, Iridium, Pinacolborane, high temperatures, pressures, olefins, ethylene, sulfide

Abstract: The catalytic hydrogenation of model alkene – cyclohexene with the use of pinacolborane is reported along with the characterization of various side products. The non-standard hydrogenation product was obtained in high yield and purity under very mild reaction conditions with the use of iridium catalyst. The exceptionally high selectivity of the hydrogenation process is described for the first time in literature.

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Joanna Niziol, Tomasz Ruman , Exceptionally Selective Catalytic Hydrogenation of Alkene with Pinacolborane , Letters in Organic Chemistry 2012; 9 (4) . https://dx.doi.org/10.2174/157017812800233723