Chiral Ligands in the Asymmetric Reformatsky Reaction

Carlos   M. R.   Ribeiro; Florence   M. C.   de Farias

doi:10.2174/157019306775474176

Abstract

Several classes of chiral ligands have been largely used to increase the enantioselectivity of asymmetric Reformatsky reaction, however, chiral diamines and aminoalcohols ligands generally shown better results. Hence, this review describes the results using chiral ligands in the very important Reformatsky reaction.

Keywords: Reformatsky reaction, ligands, zinc, aminoalcohol, diol, diamines

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Mini-Reviews in Organic Chemistry

Title: Chiral Ligands in the Asymmetric Reformatsky Reaction

Volume: 3 Issue: 1

Author(s): Carlos M. R. Ribeiro and Florence M. C. de Farias

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Keywords: Reformatsky reaction, ligands, zinc, aminoalcohol, diol, diamines

Abstract: Several classes of chiral ligands have been largely used to increase the enantioselectivity of asymmetric Reformatsky reaction, however, chiral diamines and aminoalcohols ligands generally shown better results. Hence, this review describes the results using chiral ligands in the very important Reformatsky reaction.

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Ribeiro M. R. Carlos and de Farias M. C. Florence, Chiral Ligands in the Asymmetric Reformatsky Reaction, Mini-Reviews in Organic Chemistry 2006; 3 (1) . https://dx.doi.org/10.2174/157019306775474176