Abstract
As steric repulsion, the electronic effect of catalysts also plays a crucial role in asymmetric catalysis. The influence of the electronic effect of catalysts on the enantioselectivity in asymmetric catalysis, including metal-chiral ligand complex and organocatalyst systems, was reviewed. The applicability and complexity of the influence were discussed. Rationally tuning the electronic effect of catalysts can indeed improve enantioselectivity. It is one of the important pathways to achieve the best stereoselectivity in asymmetric catalysis.
Keywords: Asymmetric catalysis, electronic effect, electron tuning, enantioselectivity, metal catalyst, organic catalyst
Related Books
Advances in Organic Synthesis
The Synthetic Methods, Structures, and Properties of the Ca-C σ Bond Organocalcium Containing Compounds
Advances in Organic Synthesis
Chemistry of Bipyrazoles: Synthesis and Applications
Advances in Organic Synthesis
Advanced Nanocatalysis for Organic Synthesis and Electroanalysis
Advances in Organic Synthesis
Advances in Organic Synthesis
9