Stereoselective Chlorination of New Type Baylis-Hillman Adducts by bis(Trichloromethyl)carbonate with the Aid of Catalytic Amount of Triphenylphosphine Oxide

Weihui      Zhong; Lingjuan      Hong; Yemin      Zheng

doi:10.2174/157017810791112469

Abstract

The chlorination of the new type Baylis-Hillman adducts by bis(trichloromethyl)carbonate (BTC) with the aid of catalytic amount of triphenylphosphine oxide (Ph3PO) was achieved with high yields and high stereoselectivities. A plausible mechanism is presented.

Keywords: New type Baylis-Hillman adducts, chlorination, triphenylphosphine oxide, bis(trichloromethyl)carbonate, stereoselectivity

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Letters in Organic Chemistry

Title: Stereoselective Chlorination of New Type Baylis-Hillman Adducts by bis(Trichloromethyl)carbonate with the Aid of Catalytic Amount of Triphenylphosphine Oxide

Volume: 7 Issue: 3

Author(s): Weihui Zhong, Lingjuan Hong and Yemin Zheng

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Keywords: New type Baylis-Hillman adducts, chlorination, triphenylphosphine oxide, bis(trichloromethyl)carbonate, stereoselectivity

Abstract: The chlorination of the new type Baylis-Hillman adducts by bis(trichloromethyl)carbonate (BTC) with the aid of catalytic amount of triphenylphosphine oxide (Ph3PO) was achieved with high yields and high stereoselectivities. A plausible mechanism is presented.

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Zhong Weihui, Hong Lingjuan and Zheng Yemin, Stereoselective Chlorination of New Type Baylis-Hillman Adducts by bis(Trichloromethyl)carbonate with the Aid of Catalytic Amount of Triphenylphosphine Oxide, Letters in Organic Chemistry 2010; 7 (3) . https://dx.doi.org/10.2174/157017810791112469