Abstract
4-(N,N-diphenylhydrazino)-3,5-dinitrobenzoic acid in reaction with 4-hydroxy-tempo, 4-aminobenzo-15- crown-5, and 1-bromoacetyl-pyrene, yielded the corresponding esters or amides, as yellow compounds. These hydrazines, by oxidation with lead dioxide, converted into the stable hydrazyl free radicals, with a purple-violet color. Same yellow hydrazines in reaction with alkali bases are converted into the corresponding salt of green color. The newly synthesized compounds were characterized by elemental analysis, IR, UV-Vis, 1H- and 13C-NMR, and EPR (where applicable). Acidbase, redox, fluorescence and complexation properties were also studied and discussed.
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