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Mini-Reviews in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-193X
ISSN (Online): 1875-6298

Sparteine and α-Isosparteine Complexes with Zn(II) and Cu(II): Structure and Spectroscopic Properties

Author(s): Beata Jasiewicz

Volume 6, Issue 4, 2009

Page: [275 - 282] Pages: 8

DOI: 10.2174/157019309789371622

Price: $65

Abstract

Coordination compounds based on bis-quinolizidine alkaloids sparteine and & -isosparteine as ligands with Zn(II) and Cu(II) salts are described from the viewpoint of their spectroscopic and structural properties. In particular the complexes of LMX2 types where L = alkaloid, X = halides (Cl-, Br-, I-), pseudo-halides (CN-, SCN-) and oxy-anions (C4H5OO-, CH3COO-, NO3-).

Keywords: Alkaloids, sparteine, α-isosparteine, Zn(II) and Cu(II) complexes, X-ray structure, spectroscopic properties


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