Synthesis and Reactions of the Optically Active Dialkyl Diselenides from the Pinane Group

Zbigniew      Rafinski; Jacek      Scianowski; Andrzej      Wojtczak

doi:10.2174/157017809788489846

Abstract

A convenient method of synthesis of the optically active dialkyl diselenides from the pinane group is described. The 3-hydroxy and 3-alkoxy derivatives of bis(cis-myrtanyl) diselenide have been obtained. The influence of a structure of the resulting diselenides on the diastereomeric excess of the methoxyselenenylation reaction and the selenocyclization have been investigated.

Keywords: Asymmetric synthesis, Diselenides, Selenium, Terpenoids

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Letters in Organic Chemistry

Title: Synthesis and Reactions of the Optically Active Dialkyl Diselenides from the Pinane Group

Volume: 6 Issue: 4

Author(s): Zbigniew Rafinski, Jacek Scianowski and Andrzej Wojtczak

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Keywords: Asymmetric synthesis, Diselenides, Selenium, Terpenoids

Abstract: A convenient method of synthesis of the optically active dialkyl diselenides from the pinane group is described. The 3-hydroxy and 3-alkoxy derivatives of bis(cis-myrtanyl) diselenide have been obtained. The influence of a structure of the resulting diselenides on the diastereomeric excess of the methoxyselenenylation reaction and the selenocyclization have been investigated.

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Rafinski Zbigniew, Scianowski Jacek and Wojtczak Andrzej, Synthesis and Reactions of the Optically Active Dialkyl Diselenides from the Pinane Group, Letters in Organic Chemistry 2009; 6 (4) . https://dx.doi.org/10.2174/157017809788489846