Metal-Catalyzed Cross-Coupling Reactions for Ferrocene Functionalization: Recent Applications in Synthesis, Material Science and Asymmetric Catalysis

V.      Mamane

doi:10.2174/157019308786242160

Abstract

Recent examples on the functionalization of the ferrocene core by means of cross-coupling reactions are reported in this review. Several methods are discussed including Negishi, Suzuki and Stille couplings for ferrocene-aryl bond formation and Sonogashira reaction for ferrocene-alkyne coupling. The properties in material science and asymmetric catalysis of the prepared ferrocenyl compounds are briefly discussed.

Keywords: Cross-coupling, palladium, ferrocene, material chemistry, asymmetric catalysis

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Mini-Reviews in Organic Chemistry

Title: Metal-Catalyzed Cross-Coupling Reactions for Ferrocene Functionalization: Recent Applications in Synthesis, Material Science and Asymmetric Catalysis

Volume: 5 Issue: 4

Author(s): V. Mamane

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Keywords: Cross-coupling, palladium, ferrocene, material chemistry, asymmetric catalysis

Abstract: Recent examples on the functionalization of the ferrocene core by means of cross-coupling reactions are reported in this review. Several methods are discussed including Negishi, Suzuki and Stille couplings for ferrocene-aryl bond formation and Sonogashira reaction for ferrocene-alkyne coupling. The properties in material science and asymmetric catalysis of the prepared ferrocenyl compounds are briefly discussed.

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Mamane V., Metal-Catalyzed Cross-Coupling Reactions for Ferrocene Functionalization: Recent Applications in Synthesis, Material Science and Asymmetric Catalysis, Mini-Reviews in Organic Chemistry 2008; 5 (4) . https://dx.doi.org/10.2174/157019308786242160