A New Application for PyOX-Ligands: The Asymmetric Henry Reaction

Ari   M.P.   Koskinen; Markku   J.   Oila; Jan   E.   Tois

doi:10.2174/157017808783330216

Abstract

C2-dissymmetric PyOX-ligands have been applied to the asymmetric Henry reaction. This widely applicable reaction is easy to perform, requires no inert atmospheres or dry solvents, and gives good selectivities. By adjusting ligand side-chains, a significant impact on selectivities was observed.

Keywords: PyOX-ligand, Henry reaction, asymmetric catalysis, copper, enantioselectivity

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Letters in Organic Chemistry

Title: A New Application for PyOX-Ligands: The Asymmetric Henry Reaction

Volume: 5 Issue: 1

Author(s): Ari M.P. Koskinen, Markku J. Oila and Jan E. Tois

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Keywords: PyOX-ligand, Henry reaction, asymmetric catalysis, copper, enantioselectivity

Abstract: C2-dissymmetric PyOX-ligands have been applied to the asymmetric Henry reaction. This widely applicable reaction is easy to perform, requires no inert atmospheres or dry solvents, and gives good selectivities. By adjusting ligand side-chains, a significant impact on selectivities was observed.

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Koskinen M.P. Ari, Oila J. Markku and Tois E. Jan, A New Application for PyOX-Ligands: The Asymmetric Henry Reaction, Letters in Organic Chemistry 2008; 5 (1) . https://dx.doi.org/10.2174/157017808783330216