Cobalt-Catalyzed Allylation of Aldimines by Allylic Acetates

Paulo      Gomes; Corinne      Gosmini; Jacques      Perichon

doi:10.2174/1570178043488518

Author(s): Paulo Gomes, Corinne Gosmini and Jacques Perichon

Volume 1, Issue 2, 2004

Page: [105 - 108] Pages: 4

DOI: 10.2174/1570178043488518

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Abstract

A Barbier-type allylation of aldimines by allylic acetates in the presence of zinc dust and a simple cobalt halide catalyst takes place in acetonitrile to give the corresponding homoallylic amines in good yields.

Keywords: allylation, homo-allylic amines, imines, cobalt halide

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Letters in Organic Chemistry

Title: Cobalt-Catalyzed Allylation of Aldimines by Allylic Acetates

Volume: 1 Issue: 2

Author(s): Paulo Gomes, Corinne Gosmini and Jacques Perichon

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Keywords: allylation, homo-allylic amines, imines, cobalt halide

Abstract: A Barbier-type allylation of aldimines by allylic acetates in the presence of zinc dust and a simple cobalt halide catalyst takes place in acetonitrile to give the corresponding homoallylic amines in good yields.

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Gomes Paulo, Gosmini Corinne and Perichon Jacques, Cobalt-Catalyzed Allylation of Aldimines by Allylic Acetates, Letters in Organic Chemistry 2004; 1 (2) . https://dx.doi.org/10.2174/1570178043488518