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Current Organic Synthesis

Editor-in-Chief

ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

Catalytic (Ni, Pd, Pt, Rh and Au) and Non-Catalytic Reactions for Atom- Economic Carbon-Sulfur, Carbon-Selenium and Carbon-Tellurium Bonds Formation

Author(s): Valentine P. Ananikov, Sergey S. Zalesskiy and Irina P. Beletskaya

Volume 8, Issue 1, 2011

Page: [2 - 52] Pages: 51

DOI: 10.2174/157017911794407692

Price: $65

Abstract

Non-catalytic and catalytic addition reactions were compared in this review, with a special attention paid to the factors controlling selectivity and yields. The scope and limitations of Ni, Pd, Pt, Rh and Au catalysts for the formation of C-S, C-Se and C-Te bonds were discussed with an impact of development of Green chemical methods.

Keywords: Catalysis, stereoselectivity, vinyl sulfides, vinyl selenides, C-S bond formation, C-Se bond formation, catalyst poisons, alkynes, vinyl chalcogenides, toxic selenium species, bis-chalcogen-substituted alkenes, Green Synthetic methods, mono-chalcogen-substituted, nucleophilic, hydrothiolation, aromatic dichalcogenides, Diphenyl Dise-lenide, isomerisation, thioselenation, di-tert-butyl, dibenzoyl peroxide, photoirradiation, Propargyl Alcohol, methyl disulfide, hexafluoro-2, phenylacetylene, Benzenethiol, Radical, Diaryl Dichalcogenides, Phenylthioalkynes, Benzeneselenol, Hydrozirconation Reac-tion


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