A Novel Approach for Ligand Promoted Palladium (II)-Catalyzed Suzuki Coupling of Aryl Iodides and Bromides with Arylboronic Acid in Aqueous Media

Shivaji   S.   Pawar; Murlidhar   S.   Shingare; Shivaji   N.   Thore

doi:10.2174/157017807782006371

Abstract

A highly efficient, environmental friendly, palladium (II) catalyzed ligand promoted Suzuki reaction in aqueous phase was developed in short reaction time (4 - 5 h) at room temperature. The key for such a successful catalytic system was the use of suitable amount of co-solvent in the aqueous phase and reuse of palladium catalyst.

Keywords: Aqueous media, suzuki-coupling reaction, PdCl2[P(Ph)3]2catalyzed, aryl iodides and bromides, boronic acid, reuse of catalyst

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Letters in Organic Chemistry

Title: A Novel Approach for Ligand Promoted Palladium (II)-Catalyzed Suzuki Coupling of Aryl Iodides and Bromides with Arylboronic Acid in Aqueous Media

Volume: 4 Issue: 7

Author(s): Shivaji S. Pawar, Murlidhar S. Shingare and Shivaji N. Thore

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Keywords: Aqueous media, suzuki-coupling reaction, PdCl2[P(Ph)3]2catalyzed, aryl iodides and bromides, boronic acid, reuse of catalyst

Abstract: A highly efficient, environmental friendly, palladium (II) catalyzed ligand promoted Suzuki reaction in aqueous phase was developed in short reaction time (4 - 5 h) at room temperature. The key for such a successful catalytic system was the use of suitable amount of co-solvent in the aqueous phase and reuse of palladium catalyst.

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Pawar S. Shivaji, Shingare S. Murlidhar and Thore N. Shivaji, A Novel Approach for Ligand Promoted Palladium (II)-Catalyzed Suzuki Coupling of Aryl Iodides and Bromides with Arylboronic Acid in Aqueous Media, Letters in Organic Chemistry 2007; 4 (7) . https://dx.doi.org/10.2174/157017807782006371