Palladium-Catalyzed Cyanation of Aryl Bromides with Potassium Hexacyanoferrate (II)

Yi-nan Cheng; Zheng Duan; Ting Li; Yangjie Wu

doi:10.2174/157017807781212111

Abstract

Simple and efficient cyclopalladated ferrocenylimine/Cu and cyclopalladated ferrocenylimine catalyzed cyanation of aryl bromides with K4[Fe(CN)6] 3H2O were described. These procedures are applicable to both activated and deactivated aryl bromides. The corresponding benzonitriles were formed in good to excellent yields.

Keywords: Palladium, copper, cyanation, catalyst, aryl bromide

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Letters in Organic Chemistry

Title: Palladium-Catalyzed Cyanation of Aryl Bromides with Potassium Hexacyanoferrate (II)

Volume: 4 Issue: 5

Author(s): Yi-nan Cheng, Zheng Duan, Ting Li and Yangjie Wu

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Keywords: Palladium, copper, cyanation, catalyst, aryl bromide

Abstract: Simple and efficient cyclopalladated ferrocenylimine/Cu and cyclopalladated ferrocenylimine catalyzed cyanation of aryl bromides with K4[Fe(CN)6] 3H2O were described. These procedures are applicable to both activated and deactivated aryl bromides. The corresponding benzonitriles were formed in good to excellent yields.

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Yi-nan Cheng , Zheng Duan , Ting Li and Yangjie Wu , Palladium-Catalyzed Cyanation of Aryl Bromides with Potassium Hexacyanoferrate (II), Letters in Organic Chemistry 2007; 4 (5) . https://dx.doi.org/10.2174/157017807781212111