[Calixarene-Based Hyperbranched Molecules with Tameand Sen Ligand Cores]

Title:[Calixarene-Based Hyperbranched Molecules with Tameand Sen Ligand Cores]

Volume: 3 Issue: 6

Author(s): Jong S. Kim, Jacques Vicens, Jong H. Jung, Sang H. Lee, Yang Kim, Mouna Mahouachi and Rym Abidi

Affiliation:

Keywords: Zn-complexation, tripodal ligands, hyperbranched molecules, Calixarenes

Abstract: Reactions between tripodal CH3C(CH2NH2)3 = tame and CH3C(CH2NHCH2CH2NH2)3 = sen with the monomethoxycarbonylmethyl ether 1 lead to the ready isolation of tame-dicalix 2, tame-tricalix 3 and sentricalix 4. Studies of complex formation of 3 and 4 with Zn(II) showed that tame residue is incapable of coordinating the metal in its N3 donor site, while Zn(II) is preferentially coordinated in the carbomethoxyamido functions and two hydroxyl groups of the calix[4]units of 4.

Cite this article as:

Kim S. Jong, Vicens Jacques, Jung H. Jong, Lee H. Sang, Kim Yang, Mahouachi Mouna and Abidi Rym, [Calixarene-Based Hyperbranched Molecules with Tameand Sen Ligand Cores], Letters in Organic Chemistry 2006; 3 (6) . https://dx.doi.org/10.2174/157017806777828439