Abstract
This review presents a recent progress in coordination and organometallic chemistry of metal complexes of chelating ligands with pyridine backbone, particularly bidentate [PN] and tridentate [PNP] aminophosphine ligands. The preparation of the ligands, their metal complexes, and the subsequent reactivity studies along with structural properties are discussed.
Keywords: Aminophosphine ligands, catalysis, chelating ligand, organometallic compounds, pyridine ligands, transition metal complexes, polydentate ligands, heterobimetallic compounds, Heterobidentate P,N ligands, asymmetric allylic alkylation, layer chromatography (TLC), asymmetric hydroboration, Stille coupling, nickel catalyzed cycloaddition reactions, asymmetric hydrogenation of highly substituted alkenes
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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