Abstract
The recent publications on the topic of the preparation of organolithium reagents by non-deprotonating methodologies and starting from non-halogenated substrates have been covered in the present revision. In this second part, transmetallation processes, mainly tin – lithium exchange, and addition to multiple bonds have been considered. Moreover, other procedures, such as carbon – carbon bond scission and the Shapiro reaction, have been included.
Keywords: Lithium, organolithiums, arene-catalysed lithiation, carbolithiation, tin/lithium exchange, transmetallation, reductive cleavage, aza-Wittig rearrangement, Organotin compounds, -aminoorganostannanes, Shapiro reaction, asymmetric cyclisation, Cyanopyridines, benzylic lithium carbanion, non-halogenated substrates
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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