Abstract
The intermolecular radical addition to the carbon atom of imine derivatives has received much less attention until recently, although the use of radical reaction in organic synthesis has continued to increase. This review highlights the intermolecular carbon-carbon bond forming reactions based on carbon radical addition to the carbon-nitrogen double bond. Particularly, the radical reactions of oxime ethers, hydrazones, sulfonylimines, ketimines, and so on are summarized. In this review, strategies for diastereo- and enantioselective radical reactions of imine derivatives are also summarized.
Keywords: Radical, imine, oxime ether, hydrazone, sulfonylimine, amine, diastereoselective, enantioselective
Call for Papers in Thematic Issues
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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