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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Research Article

Ionic Liquid@ HT- Clay Combination for Baylis -Hillman Reaction and Lactone Ceramide Analog Synthesis

Author(s): Vivek Srivastava*

Volume 21, Issue 2, 2024

Published on: 04 October, 2023

Page: [155 - 162] Pages: 8

DOI: 10.2174/1570178620666230818143230

Price: $65

Abstract

This study investigates the use of ionic liquids (ILs) immobilized on HT-clay as catalysts for the Baylis-Hillman reaction. The catalytic system comprised three different types of ILs ([HIM]Im, [BIM]Im, [EIM]Im) and exhibited high reactivity, and the B-H products were obtained in good yield, which is superior to previously reported catalytic systems, whether they were heterogeneous or homogeneous. The HT-clay immobilized with ILs also allowed for easy recovery from the reaction mass and could be recycled for up to 7 consecutive runs with only a slight decrease in activity. Moreover, the scope of our catalytic system was extended to synthesize biologically active lactone ceramide analogs using the Baylis-Hillman reaction at room temperature with (S-) Garner aldehyde and methyl acrylate. The synthesis was successful, and we obtained good yields of the desired products, highlighting the versatility of the ionic liquid immobilized HT-clay catalytic system. This study demonstrates the potential of ionic liquid immobilized HT-clay as a promising catalyst for various organic reactions. Our findings emphasize the importance of developing efficient and environmentally friendly methods for synthesizing valuable organic compounds. The results obtained from this study provide a significant contribution to the ongoing research in the field of catalysis and will be useful for developing new approaches to the synthesis of complex organic molecules.

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