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Current Nanomaterials

Editor-in-Chief

ISSN (Print): 2405-4615
ISSN (Online): 2405-4623

Research Article

Progress on Polyolefin/Graphene Nanocomposites with High Dielectric Constant and Low Dielectric Loss for Electrical Applications

Author(s): Haia Aldosari*, Nawal Madkhali, Saja Algasser and M. Khairy

Volume 9, Issue 4, 2024

Published on: 13 November, 2023

Page: [367 - 376] Pages: 10

DOI: 10.2174/2405461508666230717100734

Price: $65

Abstract

Introduction: The attached oxygen functional group in graphene oxide (GO) with layers that are about 1.1 ± 0.2 nm thick, has hindered the performance of electrical characteristics. Diminution of the oxygen functional group, and increasing the carbon/oxygen (C/O) ratio can enhance electrical conductivity.

Method: This study investigated the effect of graphene derivatives (C/O) ratios on the dielectric properties of low-density polyethylene (PE) made of metallocene, as well as polypropylene (PP) and mixtures of them. The oxygen functional groups were reduced by utilizing graphene oxide (GO) and reduced graphene oxide (rGO). The effect of GO and rGO-based polyolefin produced by solution blending while lowering the oxygen functional group is explored.

Result: The surface morphology and chemical structure were examined by using a scanning electron microscope (SEM) and Fourier Transformed Infrared Spectroscopy (FTIR). The electrical characteristics of the composite films, such as their loss factor (tan δ) and dielectric constant, permittivity and conductivity, and imaginary permittivity were examined. At room temperature, measurements were performed at frequencies ranging from 300 Hz to 8 MHz. ε'; the dielectric permittivity and imaginary permittivity (ε") of polymer/ reduced graphene oxidehowever, these values rapidly decreased with increasing frequency.

Conclusion: The alternating current conductivity of the composites was likewise shown to increase with increasing frequency.

Graphical Abstract

[1]
Verdejo R, Bernal MM, Romasanta LJ, Lopez-Manchado MA. Graphene filled polymer nanocomposites. J Mater Chem 2011; 21(10): 3301-10.
[http://dx.doi.org/10.1039/C0JM02708A]
[2]
Singh V, Joung D, Zhai L, Das S, Khondaker SI, Seal S. Graphene based materials: Past, present and future. Prog Mater Sci 2011; 56(8): 1178-271.
[http://dx.doi.org/10.1016/j.pmatsci.2011.03.003]
[3]
Galpaya D, Wang M, Liu M, Motta N, Waclawik E, Yan C. Recent advances in fabrication and characterization of graphenepolymer nanocomposites. Graphene 2012; 1(2): 30-49.
[http://dx.doi.org/10.4236/graphene.2012.12005]
[4]
Potts JR, Dreyer DR, Bielawski CW, Ruoff RS. Graphene-based polymer nanocomposites. Polymer (Guildf) 2011; 52(1): 5-25.
[http://dx.doi.org/10.1016/j.polymer.2010.11.042]
[5]
da Silva LDP, Freitas KHG, de Sousa FF. Electrical and dielectric properties of water. Scientia Plena 2017; 13: 012721.
[6]
Kremer F, Schönhals A. Broadband Dielectric Spectroscopy. Berlin, Heidelberg: Springer 2003.
[7]
Kalmykov YP. Recent Advances in Broadband Dielectric Spectroscopy. Springer 2011.
[8]
Mehedi Hassan M, Khan W, Azam A, Naqvi AH. Influence of Cr incorporation on structural, dielectric and optical properties of ZnO nanoparticles. J Ind Eng Chem 2015; 21: 283-91.
[http://dx.doi.org/10.1016/j.jiec.2014.01.047]
[9]
Belkhaoui C, Mzabi N, Smaoui H, Daniel P. Enhancing the structural, optical and electrical properties of ZnO nanopowders through (Al + Mn) doping. Results Phys 2019; 12: 1686-96.
[http://dx.doi.org/10.1016/j.rinp.2019.01.085]
[10]
Modwi A, Taha KK, Khezami L, et al. Dependence of the electrical properties of Cu-doped ZnO nanoparticles decorated by Ag atoms. Z Phys Chem 2021; 235(6): 745-67.
[http://dx.doi.org/10.1515/zpch-2019-1473]
[11]
I. Ahmad ans et al., Synthesis and characterization of silver doped zno nanoparticles for hydrogen production. J Ovonic Res 2018; 14(6): 415-27.
[12]
He F, Lau S, Chan HL, Fan J. High dielectric permittivity and low percolation threshold in nanocomposites based on poly(vinylidene fluoride) and exfoliated graphite nanoplates. Adv Mater 2009; 21(6): 710-5.
[http://dx.doi.org/10.1002/adma.200801758]
[13]
Wang L, Yang J, Cheng W, Zou J, Zhao D. Progress on Polymer Composites With Low Dielectric Constant and Low Dielectric Loss for High-Frequency Signal Transmission. Front Mater 2021; 8: 774843.
[http://dx.doi.org/10.3389/fmats.2021.774843]
[14]
Aldosari H. The effect of graphene oxide dispersion on structureproperty relationships in graphene-based polymer nanocomposites. J Nano Res 2020; 65: 97-121.
[15]
Aldosari H. The Effect of Carbon/Oxygen Ratio upon Structure-Property Relationships in Polymer/Graphene Nanocomposites. Nano Hybrids and Composites 2022; 37: 59-78.
[http://dx.doi.org/10.4028/p-72519w]
[16]
Wang X, Xing W, Song L, Yang H, Hu Y, Yeoh GH. Fabrication and characterization of graphene-reinforced waterborne polyurethane nanocomposite coatings by the sol–gel method. Surf Coat Tech 2012; 206(23): 4778-84.
[http://dx.doi.org/10.1016/j.surfcoat.2012.03.077]
[17]
Konios D, Stylianakis MM, Stratakis E, Kymakis E. Dispersion behaviour of graphene oxide and reduced graphene oxide. J Colloid Interface Sci 2014; 430: 108-12.
[http://dx.doi.org/10.1016/j.jcis.2014.05.033] [PMID: 24998061]
[18]
Eigler S, Dotzer C, Hirsch A. Visualization of defect densities in reduced graphene oxide. Carbon 2012; 50(10): 3666-73.
[http://dx.doi.org/10.1016/j.carbon.2012.03.039]
[19]
Bhawal P, Ganguly S, Chaki TK, Das NC. Synthesis and characterization of graphene oxide filled ethylene methyl acrylate hybrid nanocomposites. RSC Advances 2016; 6(25): 20781-90.
[http://dx.doi.org/10.1039/C5RA24914G]
[20]
Çiplak Z, Yildiz N, Çalimli A. Investigation of Graphene/Ag Nanocomposites Synthesis Parameters for Two Different Synthesis Methods. Fuller Nanotub Carbon Nanostruct 2015; 23(4): 361-70.
[http://dx.doi.org/10.1080/1536383X.2014.894025]
[21]
Trapalis A, Todorova N, Giannakopoulou T, et al. TiO2/graphene composite photocatalysts for NOx removal: A comparison of surfactant-stabilized graphene and reduced graphene oxide. Appl Catal B 2016; 180: 637-47.
[http://dx.doi.org/10.1016/j.apcatb.2015.07.009]
[22]
Naebe M, Wang J, Amini A, et al. Mechanical property and structure of covalent functionalised graphene/epoxy nanocomposites. Sci Rep 2014; 4(1): 4375.
[http://dx.doi.org/10.1038/srep04375] [PMID: 24625497]
[23]
Chandra R, Rustgi R. Biodegradation of maleated linear lowdensity polyethylene and starch blends. Polym Degrad Stabil 1997; 56(2): 185-202.
[http://dx.doi.org/10.1016/S0141-3910(96)00212-1]
[24]
Sarker M, Rashid MM, Molla M. Abundant High-Density Polyethylene (HDPE-2) Turns into Fuel by Using of HZSM-5 Catalyst. Journal of Fundamentals of Renewable Energy and Applications 2011; 1: 1-12.
[http://dx.doi.org/10.4303/jfrea/R110201]
[25]
Rjeb A, Tajounte L, Chafik El Idrissi M M, Letarte, A. Adnot, D. Roy and J. Kaloustian, IR spectroscopy study of polypropylene natural ageing. J Appl Polym Sci 2000; 77: 1742-8.
[http://dx.doi.org/10.1002/1097-4628(20000822)77:8<1742:AID-APP11>3.0.CO;2-T]
[26]
Lin JH, Pan YJ, Liu CF, et al. Preparation and Compatibility Evaluation of Polypropylene/High Density Polyethylene Polyblends. Materials (Basel) 2015; 8(12): 8850-9.
[http://dx.doi.org/10.3390/ma8125496] [PMID: 28793750]
[27]
Chieng B, Ibrahim N, Yunus W, Hussein M, Then Y, Loo Y. Effects of graphene nanoplatelets and reduced graphene oxide on poly(lactic acid) and plasticized poly(lactic acid): A comparative study. Polymers (Basel) 2014; 6(8): 2232-46.
[http://dx.doi.org/10.3390/polym6082232]
[28]
Yu S, Yin Y, Liu J. Silver nanoparticles in the environment. Environ Sci Process Impacts 2013; 15(1): 78-92.
[http://dx.doi.org/10.1039/C2EM30595J] [PMID: 24592429]
[29]
Xu Z, Gao H, Guoxin H. Solution-based synthesis and characterization of a silver nanoparticle–graphene hybrid film. Carbon 2011; 49(14): 4731-8.
[http://dx.doi.org/10.1016/j.carbon.2011.06.078]
[30]
Paredes JI, Villar-Rodil S, Martínez-Alonso A, Tascón JMD. Graphene oxide dispersions in organic solvents. Langmuir 2008; 24(19): 10560-4.
[http://dx.doi.org/10.1021/la801744a] [PMID: 18759411]
[31]
Xia X, Wang Y, Zhong Z, Weng GJ. A frequency-dependent theory of electrical conductivity and dielectric permittivity for graphene-polymer nanocomposites. Carbon 2017; 111: 221-30.
[http://dx.doi.org/10.1016/j.carbon.2016.09.078]
[32]
Xie L, Huang X, Wu C, Jiang P. Core-shell structured poly(methyl methacrylate)/BaTiO3 nanocomposites prepared by in situ atom transfer radical polymerization: a route to high dielectric constant materials with the inherent low loss of the base polymer. J Mater Chem 2011; 21(16): 5897.
[http://dx.doi.org/10.1039/c0jm04574h]
[33]
Zhi X, Mao Y, Yu Z, et al. γ-Aminopropyl triethoxysilane functionalized graphene oxide for composites with high dielectric constant and low dielectric loss. Compos, Part A Appl Sci Manuf 2015; 76: 194-202.
[http://dx.doi.org/10.1016/j.compositesa.2015.05.015]
[34]
Yousefi N, Sun X, Lin X, et al. Highly aligned graphene/polymer nanocomposites with excellent dielectric properties for highperformance electromagnetic interference shielding. Adv Mater 2014; 26(31): 5480-7.
[http://dx.doi.org/10.1002/adma.201305293] [PMID: 24715671]
[35]
Monti M, Armentano I, Faiella G, et al. Toward the microstructure–properties relationship in MWCNT/epoxy composites: Percolation behavior and dielectric spectroscopy. Compos Sci Technol 2014; 96: 38-46.
[http://dx.doi.org/10.1016/j.compscitech.2014.03.008]
[36]
Ning N, Bai X, Yang D, et al. Dramatically improved dielectric properties of polymer composites by controlling the alignment of carbon nanotubes in matrix. RSC Advances 2014; 4(9): 4543-51.
[http://dx.doi.org/10.1039/C3RA45769A]
[37]
Han L, Wang H, Tang Q, et al. Preparation of graphene/polypropylene composites with high dielectric constant and low dielectric loss via constructing a segregated graphene network. RSC Advances 2021; 11(60): 38264-72.
[http://dx.doi.org/10.1039/D1RA06138K] [PMID: 35498095]
[38]
Qiu J, Gu Q, Sha Y, Huang Y, Zhang M, Luo Z. Preparation and application of dielectric polymers with high permittivity and low energy loss: A mini review. J Appl Polym Sci 2022; 139(24): 52367.
[http://dx.doi.org/10.1002/app.52367]
[39]
Lin SY, Ye YM, Chen EC, Wu TM. Low dielectric properties and transmission loss of polyimide/organically modified hollow silica nanofiber composites. Polymers 2022; 14(20): 4462.
[http://dx.doi.org/10.3390/polym14204462] [PMID: 36298038]

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