Login Register Cart 0
Generic placeholder image

Current Applied Polymer Science

Editor-in-Chief

ISSN (Print): 2452-2716
ISSN (Online): 2452-2724

Back
Journal Home About Journal Editorial Board Journal Insight Current Issue Volumes/Issues
Subscribe
Research Article

Mechanical Properties and Molecular Transport Behavior of NR/Clay and ENR/Clay Composites

Author(s): Rakesh Reghunath, Aji P. Mathew and Soney C. George*

Volume 6, Issue 1, 2023

Published on: 09 June, 2023

Page: [39 - 47] Pages: 9

DOI: 10.2174/2452271606666230504110847

Price: $65

Abstract

Introduction: Natural rubber and epoxidized natural rubber composites reinforced with clay have been synthesized in this study using two roll mixing mill.

Objective: The aim of the research work was to investigate the influence of clay on the overall performance of NR and ENR based composites.

Methods: The effect of clay concentration on basic mechanical properties and molecular transport phenomena of the elastomeric composites was analyzed. Tensile strength and tear strength variation as a function of clay concentration were studied.

Results: It was found that as clay concentration increased up to 4 phr, tensile strength improved up to 22.5 MPa and tear strength up to 32 MPa, beyond which it went down. It was also found that corresponding to 4 phr clay concentrations, the crosslink density of the composite was at a maximum of 1.45 gmol/cc.

Conclusion: As the clay contents are added into the elastomeric matrix system, initially there is a decrease in the swelling coefficient, but later at higher loading, the swelling coefficient increases due to the agglomeration of clay particles in the matrix.

« Previous Next »
Graphical Abstract

[1]
Ewulonu CM, Obele CM, Arukalam IO, Odera SR. Effects of local clay incorporation technique on the mechanical. In: Development of polymer composites using waste resources. Int J Appl Sci Eng Res 2015; 4(3): 307-20.
[2]
Universit SS, Sud B, Universit YG. Tensile stress relaxation studies of TiO2 and natural rubber composites. Industrial &Engineering Chemistry Research 2009; 48: 3410-6.
[3]
Ochigbo SS, Luyt AS. Mechanical and morphological properties of films based on ultrasound treated titanium dioxide dispersion/natural rubber latex. International Journal of Composite Materials 2011; 1(1): 7-13.
[4]
Argonne MS. Improving reinforcement of natural rubber by networking of activated carbon nanotubes. Carbon 2008; 46(7): 1037-45.
[5]
Imoisili PE, Ukoba KO, Adejugbe IT, Adgidzi D, Olusunle SOO. Mechanical properties of rice husk/carbon black hybrid natural rubber composite. Chemistry and Materials Research 2013; 3(8): 12-6.
[6]
Jo JO, Saha P, Kim NG, Chang Ho C, Kim JK. Development of nanocomposite with epoxidized natural rubber and functionalized multiwalled carbon nanotubes for enhanced thermal conductivity and gas barrier property. Mater Des 2015; 83: 777-85.
[http://dx.doi.org/10.1016/j.matdes.2015.06.045]
[7]
Tabsan N, Wirasate S, Suchiva K. Abrasion behavior of layered silicate reinforced natural rubber. Wear 2010; 269: 394-404.
[8]
Rath JP, Chaki TK, Khastgir D. Development of natural rubber-fibrous nano clay attapulgite composites. Effect of Chemical Treatment of Filler on Mechanical and Dynamic Mechanical Properties of Composites. Procedia Chem 2012; 4: 131-7.
[9]
Jacob Ansu Kurian, Philp K, Santhosh A Prem A. Transport properties of natural rubber latex layered clay nanocomposites. Journal of J Applied Polymer Science 2008; 108: 2623-9.
[10]
Tan Jing-Hua-. Effects of epoxidized natural rubber as a compatibilizer on latex compounded natural rubber-clay nanocomposites. Journal of Polymer Engineering 2016; 37: 43-51.
[11]
George SC. The fabrication and properties of natural rubber-clay nanocomposites. J Poly Test 2015; 51(11): 165-73.
[12]
Lakshmipriya S, Anil Kumar S, Nandakumar K. Sabu Thoma,“Influence of POSS fillers on the transport properties of natural rubber nanocomposites”. Polym Compos 2019; 40(8): 3020-31.
[13]
Abhita. Analysis of diffusion characteristics for aromatic solventsthrough carbon black filled natural rubber/butadienerubber blends. Polym Compos 2021; 42(1): 375-96.
[14]
Aparna. Transport behavior of aromatic hydrocarbons through coconut shell powder filled thermoplastic polyurethane/natural rubber blend-composites. AIP Conference Proceedings 2017; 1849.
[15]
Sareena C, Ramesan MT, Purushothaman E. Transport studies of peanut shell powder reinforced natural rubber composites in chlorinated solvents. Fibers Polym 2013; 14(10): 1674-87.
[http://dx.doi.org/10.1007/s12221-013-1674-2]
[16]
Varghese S, Karger-Kocsis J. Natural rubber-based nanocomposites by latex compounding with layered silicates. Polymer 2003; 44(17): 4921-7.
[http://dx.doi.org/10.1016/S0032-3861(03)00480-4]
[17]
Maria Hanna, Lyczko NathalieNzihou, Ange N, et al. Transport of organic solvents through natural rubber/nitrile rubber/organically modified montmorillonite nanocomposites. J Mater Sci 2013; 48(15): 5373-86.
[18]
Joseph S, Jose AJ, Wilson R, Thomas S, Joseph K. Molecular transport of aromatic solvents through oil palm micro fiber filled nitrile rubber composites. Mater Today Proc 2019; 9: 266-78.
[19]
Datta J. Preparation, morphology and properties of natural rubber composites filled with untreated short jute fibres. Polymer Buttetin 2016; 74: 763-82.
[20]
Jose T. Multifunctional multi-walled carbon nanotube reinforced natural rubber nanocomposites. Indstrial Crops and Products 2017; 105: 63-73.
[21]
Sarkarat M, Lanagan M, Ghosh D, Lottes A, Budd K, Rajagopalan R. and High field dielectric properties of clay filled silicone rubber composites. Mater Today Commun 2020; 23: 100947.
[22]
Garing CL, Pajarito B. Effect of clay loading on the water resistance of ternary-filled natural rubber composites. Mater Today Proc 2020; 33: 1959-62.
[23]
Abhisha VS, Augustine A, Joseph J, Thomas SP, Stephen R. Effect of halloysite nanotubes and organically modified bentonite clay hybrid filler system on the properties of natural rubber. J Elastomers Plast 2020; 52(5): 432-52.
[http://dx.doi.org/10.1177/0095244319865573]

Rights & Permissions Print Cite
© 2024 Bentham Science Publishers | Privacy Policy